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Rate constants for mammalian glutaredoxins and poplar GrxS12 range from 2.5 10 4 to 2 10 6 M 1 s 1 and also support a rate-limiting reductive half-reaction 19,20,21,37

Conventional treatments include NSAIDs, corticosteroid injections, and hyaluronic acid (HA) injections , but these often provide only temporary symptom relief without addressing the underlying pathology

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Rats with pancreatitis exhibit elevated levels of reactive oxygen species (ROS) and MMPs, manifesting in glycocalyx and mitochondrial damage [17, 18]