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The unusual -glutamyl bond makes it resistant to most peptidases

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These barriers are physically represented by the so-called tight junctions between brain endothelial cells and epithelial cells, attributed to the special proteins such as occludin, claudins, and the associated proteins zona occludens (ZO-1, ZO-2, and ZO-3), which are highly expressed in brain endothelium (Chen et al., 2009

Al-Kuraishy HM, Al-Gareeb AI, Saad HM, Batiha GE-S (2023) Long-term use of metformin and Alzheimers disease: beneficial or detrimental effects